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Nine members of a family of nine-membered cyclic coordination clusters; Fe6Ln3 wheels (Ln = Gd to Lu and Y)

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Description
We report a family of isostructural nonanuclear Fe(III)-Ln(III) cyclic coordination clusters [Fe(III)(6)Ln(III)(3)(μ-OMe)9(vanox)6(benz)6]. (Ln = Tb (1), Dy (2), Ho (3), Er (4), Tm (5), Yb (6), Lu (7), Y (8) and Gd (9)), containing an odd number of metal ions. The planar cyclic coordination cluster cores are built up from three [Fe2Ln] subunits.
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Chemical communications (Cambridge, England), 18 January 2016, Vol.52(5), pp.1021-4
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peer_reviewed
Identifier
1364-548X (E-ISSN)
26592179 Version (PMID)
10.1039/c5cc08887a (DOI)