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    4-Lump kinetic model for vacuum gas oil hydrocracker involving hydrogen consumption

    Sadighi, Sepehr, Ahmad, Arshad, Rashidzadeh, Mehdi
    Korean Journal of Chemical Engineering, 2010, Vol.27(4), pp.1099-1108 [Peer Reviewed Journal]
    Springer Science & Business Media B.V.
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    Title: 4-Lump kinetic model for vacuum gas oil hydrocracker involving hydrogen consumption
    Author: Sadighi, Sepehr; Ahmad, Arshad; Rashidzadeh, Mehdi
    Subject: Vacuum Gas Oil ; Hydrotreating ; Hydrocracking ; Lump Kinetic Model ; Hydrogen Consumption
    Description: A 4-lump kinetic model including hydrogen consumption for hydrocracking of vacuum gas oil in a pilot scale reactor is proposed. The advantage of this work over the previous ones is consideration of hydrogen consumption, imposed by converting vacuum gas oil to light products, which is implemented in the kinetic model by a quadratic expression as similar as response surface modeling. This approach considers vacuum gas oil (VGO) and unconverted oil as one lump whilst others are distillate, naphtha and gas. The pilot reactor bed is divided into hydrotreating and hydrocracking sections which are loaded with different types of catalysts. The aim of this paper is modeling the hydrocracking section, but the effect of hydrotreating is considered on the boundary condition of the hydrocracking part. The hydrocracking bed is considered as a plug flow reactor and it is modeled by the cellular network approach. Initially, a kinetic network with twelve coefficients and six paths is considered. But following evaluation using measured data and order of magnitude analysis, the three route passes and one activation energy coefficient are omitted; thus the number of coefficients is reduced to five. This approach improves the average absolute deviation of prediction from 7.2% to 5.92%. Furthermore, the model can predict the hydrogen consumption for hydrocracking with average absolute deviation about 8.59% in comparison to those calculated from experimental data.
    Is part of: Korean Journal of Chemical Engineering, 2010, Vol.27(4), pp.1099-1108
    Identifier: 0256-1115 (ISSN); 1975-7220 (E-ISSN); 10.1007/s11814-010-0172-0 (DOI)

    • Article
    Select

    4-Lump kinetic model for vacuum gas oil hydrocracker involving hydrogen consumption

    Sepehr Sadighi, Arshad Ahmad, Mehdi Rashidzadeh
    The Korean journal of chemical engineering, July 2010, Vol.27(4), pp.1099-1108 [Peer Reviewed Journal]
    Korea Citation Index (NRF)
    Available
    More…
    Title: 4-Lump kinetic model for vacuum gas oil hydrocracker involving hydrogen consumption
    Author: Sepehr Sadighi; Arshad Ahmad; Mehdi Rashidzadeh
    Subject: 화학공학 ; Engineering
    Description: A 4-lump kinetic model including hydrogen consumption for hydrocracking of vacuum gas oil in a pilot scale reactor is proposed. The advantage of this work over the previous ones is consideration of hydrogen consumption,imposed by converting vacuum gas oil to light products, which is implemented in the kinetic model by a quadratic expression as similar as response surface modeling. This approach considers vacuum gas oil (VGO) and unconverted oil as one lump whilst others are distillate, naphtha and gas. The pilot reactor bed is divided into hydrotreating and hydrocracking sections which are loaded with different types of catalysts. The aim of this paper is modeling the hydrocracking section, but the effect of hydrotreating is considered on the boundary condition of the hydrocracking part. The hydrocracking bed is considered as a plug flow reactor and it is modeled by the cellular network approach. Initially,a kinetic network with twelve coefficients and six paths is considered....
    Is part of: The Korean journal of chemical engineering, July 2010, Vol.27(4), pp.1099-1108
    Identifier: 0256-1115 (ISSN); 1975-7220 (E-ISSN)